Infrared evidence for the transmission of electronic effects through a metal atom in a series of new cadmium complexes

Haigh, J.M. and van Dam, M.A. and Thornton, D.A. (1967) Infrared evidence for the transmission of electronic effects through a metal atom in a series of new cadmium complexes. Zietschrift fur anorganische und allgemeine Chemie, 355 . pp. 94-103. ISSN 0044-2313

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Abstract

A series of novel cadmium complexes has been synthesized from the reaction of cadmium chloride, bromide and iodide with primary aromatic amines. The complexes are either mononuclear or polynuclear according to the nature of the halide and amine employed. A possible mechanism for their formation is proposed. The N - H stretching and bending frequencies are linearly related to the electronegativity of the co-ordinated halogen, indicating that the electron withdrawing capacity of the halogen is transmitted through the cadmium atom.

Item Type:Article
Uncontrolled Keywords:cadmium complexes; infrared; metal atom
Subjects:Y Unknown > Subjects to be assigned
Divisions:Faculty > Faculty of Pharmacy
ID Code:583
Deposited By: Prof John Haigh
Deposited On:05 Jun 2007
Last Modified:06 Jan 2012 16:18
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